23
English
eng
Khan, Z.
Contributor
<p><span style="color: rgb(31, 31, 31); font-family: ElsevierGulliver, Georgia, "Times New Roman", Times, STIXGeneral, "Cambria Math", "Lucida Sans Unicode", "Microsoft Sans Serif", "Segoe UI Symbol", "Arial Unicode MS", serif; font-size: 16px;">In this paper we report the effect of poly(vinyl alcohol) (PVA) on the </span><a href="https://www.sciencedirect.com/topics/chemistry/silver" title="Learn more about silver from ScienceDirect's AI-generated Topic Pages" class="topic-link" style="margin: 0px; padding: 0px; background-color: transparent; word-break: break-word; text-decoration-line: underline; text-decoration-thickness: 1px; text-decoration-color: rgb(31, 31, 31); color: rgb(31, 31, 31); text-underline-offset: 1px; font-family: ElsevierGulliver, Georgia, "Times New Roman", Times, STIXGeneral, "Cambria Math", "Lucida Sans Unicode", "Microsoft Sans Serif", "Segoe UI Symbol", "Arial Unicode MS", serif; font-size: 16px;">silver</a><span style="margin: 0px; padding: 0px; color: rgb(31, 31, 31); font-family: ElsevierGulliver, Georgia, "Times New Roman", Times, STIXGeneral, "Cambria Math", "Lucida Sans Unicode", "Microsoft Sans Serif", "Segoe UI Symbol", "Arial Unicode MS", serif; font-size: 16px;"><span style="margin: 0px; padding: 0px;"> nanoparticles formation of different morphologies by using silver nitrate and <a href="https://www.sciencedirect.com/topics/chemistry/citric-acid" title="Learn more about citric acid from ScienceDirect's AI-generated Topic Pages" class="topic-link" style="margin: 0px; padding: 0px; background-color: transparent; word-break: break-word; text-decoration-line: underline; text-decoration-thickness: 1px; text-decoration-color: rgb(31, 31, 31); color: rgb(31, 31, 31); text-underline-offset: 1px;">citric acid</a><span style="margin: 0px; padding: 0px;"> as the oxidant and reductant, respectively, for the first time. Our <a href="https://www.sciencedirect.com/topics/chemistry/transmission-electron-microscopy" title="Learn more about transmission electron microscopy from ScienceDirect's AI-generated Topic Pages" class="topic-link" style="margin: 0px; padding: 0px; background-color: transparent; word-break: break-word; text-decoration-line: underline; text-decoration-thickness: 1px; text-decoration-color: rgb(31, 31, 31); color: rgb(31, 31, 31); text-underline-offset: 1px;">transmission electron microscopy</a> (TEM) results suggest that the presence of PVA has significant impact on the size, shape, and the size distribution of the silver nanoparticles. The reaction follows a zero-order kinetics in [citric acid] as well as in [silver(I)] in the absence and presence of PVA. It was found that PVA and </span></span><a href="https://www.sciencedirect.com/topics/chemistry/cetyltrimethylammonium-bromide" title="Learn more about cetyltrimethylammonium bromide from ScienceDirect's AI-generated Topic Pages" class="topic-link" style="margin: 0px; padding: 0px; background-color: transparent; word-break: break-word; text-decoration-line: underline; text-decoration-thickness: 1px; text-decoration-color: rgb(31, 31, 31); color: rgb(31, 31, 31); text-underline-offset: 1px;">cetyltrimethylammonium bromide</a> (CTAB) concentrations show no significant effects on the rate of CTAB-stabilized silver nanoparticles formation, whereas in presence of PVA, the reaction rate increases with (CTAB). Both spectrophotometric and TEM measurement demonstrated that the orange silver sol consists of aggregates, whereas the purple sol does not contain the aggregated arrangement. On the basis of various observations, the most plausible mechanism has been envisaged.</span><br></p>
Elsevier Ltd.
October 2012
pdf
Arabian Journal of Chemistry
Kinetics of silver nanoparticle growth in aqueous polymer solutions: 1st Nano Update
mixed material
Elsevier Ltd.